Muscle memory will definitely play a role, and for the good if you have a good place for cheek weld and consistent hold (so when you bring the rifle up and shouldered the center of the scope is centered with the eye). If you are shouldering the rifle and hunting for the dot, and hunting for the game or target, then you likely need to move either the cheek.piece or scope up or down.
One way to tell is to the shoulder the rifle several times with your eyes closed. Then shoulder it and open them. The scope should be centered when you open your eyes. If not, either raise it or lower it with the mounting rings, a cheek.piece, or work out a different memorized hold. I read that it takes about 63 repetitions to develop muscle memory.