You mean like a revolver round, jumping from cylinder to forcing cone? I wouldn't change the geometry of the leading edge of the rifling, I'm sure a lot of engineering has gone into those particular angles in respect to the helix angle of the rifling itself. It may very well be set up to "cut" the rifling into the projectile rather than deform it to the shape of the bore. Some guys get insane about this stuff and would shoot you for pulling a brush down their barrel 1 time....... especially serious rimfire target shooters, they're fanatical about that portion of the barrel in which the rifling engages the projectile........which is kind of ironic because again your talking about low power, small bore rifles shooting soft projectiles at RELATIVELY low velocity. Interesting.
As to seating the projectile against or started into the rifling, yes.......that's the way professional shooters/reloaders using "collet style" dies seat their projectiles, even going so far as to use only "fire formed" brass for competition ammo. In other words, if the brass case hasn't already been fire formed to fit THAT particular rifle chamber it will not be used in competition. On top of that, they put an index mark on the round so that it is loaded oriented to the chamber the exact same way every time. Like I said, it gets crazy. Crazy.....but they can shoot through the same hole all day long.