how do you de-pressurize the air from a PCP cylinder?

If you leave the PCP EMPTY for prolonged periods then you may find leak problems in the future. Easiest no brainer way to degas is to keep shooting it at targets and critters just have fun till it pisses all the air out at the end that way you enjoy shooting it down and not waste air.

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Actually it is better for a pcp to stay pressurized. Unless your working on it as stated above. Now as a general rule you would first research your rifle and see if there are any factory recommendations for degas procedures. The marauder has a tool for example. Or you can shoot it down. that can be a quick process for larger calibers or take forever with a 177. The other option is to point your air guage away from yourself and start unscrewing slowly until you hear a hiss. Walk away and come back. If the hissing stopped crack it a little more until you hear it hiss again. Repeat as necessary. Work on your gun and fill it again right after. Uncharged guns get dust inside the tube and components. It will require a full teardown and clean up if this happens. Leave it charged! If you good luck.