Uhm toku, you're sorely mistaken if you believe a smaller caliber will make more power than a larger caliber with the same bullet weight, pressure, and barrel length...
.25 cal --- 19.5" barrel ---- 2000 psi --- Full bore porting ---- 25.4 gr
ROUNDDOWN(SQRT((ROUNDDOWN(((25.4*2)+ROUNDDOWN((0.25^2 * 3.14159/4) * 2000 * (19.5 / 12) / 2,2))/2)*450240)*0.9/25.4))
= 1018 fps / 58.46 FPE
.22 cal --- 19.5" barrel ---- 2000 psi --- Full bore porting ---- 25.4 gr
ROUNDDOWN(SQRT((ROUNDDOWN(((25.4*2)+ROUNDDOWN((0.22^2 * 3.14159/4) * 2000 * (19.5 / 12) / 2,2))/2)*450240)*0.9/25.4))
= 945 fps / 50.4 FPE
As you can see the larger caliber output is 13% more energy output, and incidentally the difference between the .22 and .25 caliber or the percent increase is equally 13%...
And its FPS x FPS x gr Divided by 450240 = FPE not FPS x FPS x gr Divided by 540240 = FPE
-Matt
Plese explain how the .25 can obtain a higher velocity using the same PSI and Volume of air? That would be like saying a .50 cal being the same weight using the same pressure and air volume in the same lenght barrel can gain higher FPS. NOT Possible!
The larger caliber requires more volume of air.
Again there are too many unknowns.
If I'm shooting a .22 25.4 gr at 1000 FPS
And a .25 25.4 grain at 1000 FPS
My FPE Would be exactly the same! Do the math!
But I'm saying that it would require more air volume to get the .25 up to the same speed as the .22. simply because of volume it would be that the .22 would have a slight advantage.