No good reason for an air rifle as far as I know, but it can be advantageous for close-quarters combat...the real kind or paintball and such:
View attachment 365007 Why Canted Works When fractions of a second matterRUN CANTED™ Why Canted Works When fractions of a second matterRUN CANTED™ Blindfold Test — your natural shooting position. Blindfold Test — your natural shooting position. If you're holding a CQB weaponnaturally, it will be canted. If you're...
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For air rifles, the very slight cant which can arise from using an 11mm mount on a 3/8” rail, or vice-versa, doesn’t make any difference when the scope reticle is oriented correctly. Granted if the offset is enough that one finds it aesthetically annoying, by all means use a self-centering mount like BKL, but there is no need in terms of eliminating cant error.