.177 will shoot 'straighter' than the others - sort of like comparing .17HMR to .22LR
While they're very accurate and will travel far, due to their lighter weight, they're more effected by their surroundings..
Air/wind, humidity/temp, etc. With .22, they have more of an arc, but, hold their own in the wind better,
as do the other heavier calibers, but, with more weight, more air / pressure / power is needed to send em' flying..
As mentioned above - BC is a great thing to find out and know when comparing different types of ammo.

Sam -
PS: I shot .177 for years and years: Multi-Pumps and Springers.
With PCP, .22 cal is my go-to, and .25 if/when I just want a bit more knock down / destruction power..
The .22 cal are amazingly accurate also. As are the .25s
Efficiency wise - when power/weight factors in, I'd assume that .22 is still the way to go.
I don't shoot anything larger cal than .25, so I won't speak for anything big-bore..
Only for what I use, and as of right now, I've only used the .22 and .25 up to 75 yards at my old range.