DaveF,
Getting the different components to "align" can be a bit tricky - but when it happens - you'll love it. I have a Bobcat MK2 (.25) and the ChairGun app is spot on with real world results.
Some thoughts for you... time to check a number of things.
Are you shooting level (or canting errors)? Is your scope reticle level?
Is your Bobcat power setting on HIGH?
Re-chrony your gun lately?
Accept the BC value for your pellet via the Chairgun app - trust me - it will likely be close enough. Just make sure that the other performance and environmental data points are correct.
Measure target distances with a tape measure or an accurate range finder - verify! If your scope distance indicator is way off - you might have to re-calibrate that by loosening set screw - adjust to proper measured distance then re-tighten. BTW - scope distance indicators sometimes make for lousy distance measuring tools - its primarily there to reduce parallax.
If you have been making numerous turret adjustments, recenter your scope erector tube (use the rotate on box grooves method as that is the best method (see youtube) - Hawke recommends NO other method). Scopes that have been adjusted beyond their optimum optical/mechanical range are a HUGE contributor to "accuracy" issues. The guys at Hawke Optics take calls all day long from customers with "broken" scopes (read: user error).
One other important note - when first zeroing your scope - adjustable mounts should do the heavy lifting in terms of bringing the POI close to bullseye. It's a bad sign to shoot once and then crank the turrets over and over... that leads to many scope accuracy/parallax issues). Turrets are for very fine adjustments/small distances.
Did you adjust your front scope ocular eyepiece for your specific vision? Remember - you are adjusting that so the
RETICLE is clear - not the distant image. And, if you did change the front ocular to accommodate your vision you have now changed the length of the scope - which, you guessed it, now changes your scope magnification from the factory design. To "re-calibrate" - you need to set scope to 10x (which is true mil-dot for the Eclipse) and set a ruler out - adjust magnification so that ONE mil-dot distance =3.6 inches at 100 yards (or 1.8 inches at 50 yards, or .9 inches at 25 yards, etc.) Once re-calibrated - mark your new power indicator position on the scope so that its accurate through the magnification ranges.
Finally, after entering your numbers into ChariGun - when I select 795 fps, I show POI at 25 yards to be .75 inches high (as per your experience) and .82 mil-dot (10X) and 1.63 mil-dot at 20x. Re-chrony and check power settings.
Good luck and keep us all posted